2-[(4-tert-Butyl-anilino)(phen-yl)meth-yl]cyclo-hexa-none

Hoong Kun Fun, Suchada Chantrapromma, Sankappa Rai, Prakash Shetty, Arun M. Isloor

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

In the mol-ecule of the title compound, C23H29NO, the cyclo-hexa-none ring has been distorted from the standard chair conformation by the ketone group such that part of the ring is almost flat. The remaining [(4-tert-butyl-anilino)(phen-yl)meth-yl] portion of the mol-ecule is in an equatorial position on the cyclo-hexa-none ring. The dihedral angle between the two benzene rings is 81.52 (8)°. In the crystal packing, mol-ecules are linked by N - H⋯O hydrogen bonds into infinite one-dimensional chains along the a axis and these chains are stacked down the c axis. The crystal structure is further stabilized by weak C - H⋯O and C - H⋯π inter-actions.

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume65
Issue number3
DOIs
Publication statusPublished - 18-03-2009

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Dihedral angle
Benzene
Ketones
Conformations
Hydrogen bonds
Crystal structure
Crystals
rings
ketones
seats
dihedral angle
benzene
hydrogen bonds
crystal structure
crystals

All Science Journal Classification (ASJC) codes

  • Condensed Matter Physics
  • Materials Science(all)
  • Chemistry(all)

Cite this

Fun, Hoong Kun ; Chantrapromma, Suchada ; Rai, Sankappa ; Shetty, Prakash ; Isloor, Arun M. / 2-[(4-tert-Butyl-anilino)(phen-yl)meth-yl]cyclo-hexa-none. In: Acta Crystallographica Section E: Structure Reports Online. 2009 ; Vol. 65, No. 3.
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abstract = "In the mol-ecule of the title compound, C23H29NO, the cyclo-hexa-none ring has been distorted from the standard chair conformation by the ketone group such that part of the ring is almost flat. The remaining [(4-tert-butyl-anilino)(phen-yl)meth-yl] portion of the mol-ecule is in an equatorial position on the cyclo-hexa-none ring. The dihedral angle between the two benzene rings is 81.52 (8)°. In the crystal packing, mol-ecules are linked by N - H⋯O hydrogen bonds into infinite one-dimensional chains along the a axis and these chains are stacked down the c axis. The crystal structure is further stabilized by weak C - H⋯O and C - H⋯π inter-actions.",
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2-[(4-tert-Butyl-anilino)(phen-yl)meth-yl]cyclo-hexa-none. / Fun, Hoong Kun; Chantrapromma, Suchada; Rai, Sankappa; Shetty, Prakash; Isloor, Arun M.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 65, No. 3, 18.03.2009.

Research output: Contribution to journalArticle

TY - JOUR

T1 - 2-[(4-tert-Butyl-anilino)(phen-yl)meth-yl]cyclo-hexa-none

AU - Fun, Hoong Kun

AU - Chantrapromma, Suchada

AU - Rai, Sankappa

AU - Shetty, Prakash

AU - Isloor, Arun M.

PY - 2009/3/18

Y1 - 2009/3/18

N2 - In the mol-ecule of the title compound, C23H29NO, the cyclo-hexa-none ring has been distorted from the standard chair conformation by the ketone group such that part of the ring is almost flat. The remaining [(4-tert-butyl-anilino)(phen-yl)meth-yl] portion of the mol-ecule is in an equatorial position on the cyclo-hexa-none ring. The dihedral angle between the two benzene rings is 81.52 (8)°. In the crystal packing, mol-ecules are linked by N - H⋯O hydrogen bonds into infinite one-dimensional chains along the a axis and these chains are stacked down the c axis. The crystal structure is further stabilized by weak C - H⋯O and C - H⋯π inter-actions.

AB - In the mol-ecule of the title compound, C23H29NO, the cyclo-hexa-none ring has been distorted from the standard chair conformation by the ketone group such that part of the ring is almost flat. The remaining [(4-tert-butyl-anilino)(phen-yl)meth-yl] portion of the mol-ecule is in an equatorial position on the cyclo-hexa-none ring. The dihedral angle between the two benzene rings is 81.52 (8)°. In the crystal packing, mol-ecules are linked by N - H⋯O hydrogen bonds into infinite one-dimensional chains along the a axis and these chains are stacked down the c axis. The crystal structure is further stabilized by weak C - H⋯O and C - H⋯π inter-actions.

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