2,4-Dimethyl-N-phenyl-benzene-sulfonamide

B. Thimme Gowda, Sabine Foro, P. G. Nirmala, K. S. Babitha, Hartmut Fuess

Research output: Contribution to journalArticle

17 Citations (Scopus)

Abstract

The asymmetric unit of the crystal structure of the title compound, C 14H15NO2S, contains two mol-ecules. The conformations of the N - C bonds in the C - SO2 - NH - C segments of the structure have trans and gauche torsion angles with the S=O bonds. Furthermore, the torsion angles of the C - SO2 - NH - C groups in the two mol-ecules are 46.1 (3) (glide image of mol-ecule 1) and 47.7 (3)° (mol-ecule 2). The ortho-methyl groups in the sulfonyl benzene ring are oriented away from the S=O bonds. The two benzene rings are tilted relative to each other by 67.5 (1) and 72.9 (1)° in the two mol-ecules. N - H⋯O and C - H⋯O hydrogen bonds pack the mol-ecules into one-dimensional chains in different directions, resulting in a two-dimensional network.

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume65
Issue number3
DOIs
Publication statusPublished - 2009

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Sulfonamides
Benzene
Torsional stress
torsion
benzene
rings
Conformations
Hydrogen bonds
Crystal structure
hydrogen bonds
crystal structure
Direction compound

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

Gowda, B. Thimme ; Foro, Sabine ; Nirmala, P. G. ; Babitha, K. S. ; Fuess, Hartmut. / 2,4-Dimethyl-N-phenyl-benzene-sulfonamide. In: Acta Crystallographica Section E: Structure Reports Online. 2009 ; Vol. 65, No. 3.
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abstract = "The asymmetric unit of the crystal structure of the title compound, C 14H15NO2S, contains two mol-ecules. The conformations of the N - C bonds in the C - SO2 - NH - C segments of the structure have trans and gauche torsion angles with the S=O bonds. Furthermore, the torsion angles of the C - SO2 - NH - C groups in the two mol-ecules are 46.1 (3) (glide image of mol-ecule 1) and 47.7 (3)° (mol-ecule 2). The ortho-methyl groups in the sulfonyl benzene ring are oriented away from the S=O bonds. The two benzene rings are tilted relative to each other by 67.5 (1) and 72.9 (1)° in the two mol-ecules. N - H⋯O and C - H⋯O hydrogen bonds pack the mol-ecules into one-dimensional chains in different directions, resulting in a two-dimensional network.",
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2,4-Dimethyl-N-phenyl-benzene-sulfonamide. / Gowda, B. Thimme; Foro, Sabine; Nirmala, P. G.; Babitha, K. S.; Fuess, Hartmut.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 65, No. 3, 2009.

Research output: Contribution to journalArticle

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AU - Gowda, B. Thimme

AU - Foro, Sabine

AU - Nirmala, P. G.

AU - Babitha, K. S.

AU - Fuess, Hartmut

PY - 2009

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N2 - The asymmetric unit of the crystal structure of the title compound, C 14H15NO2S, contains two mol-ecules. The conformations of the N - C bonds in the C - SO2 - NH - C segments of the structure have trans and gauche torsion angles with the S=O bonds. Furthermore, the torsion angles of the C - SO2 - NH - C groups in the two mol-ecules are 46.1 (3) (glide image of mol-ecule 1) and 47.7 (3)° (mol-ecule 2). The ortho-methyl groups in the sulfonyl benzene ring are oriented away from the S=O bonds. The two benzene rings are tilted relative to each other by 67.5 (1) and 72.9 (1)° in the two mol-ecules. N - H⋯O and C - H⋯O hydrogen bonds pack the mol-ecules into one-dimensional chains in different directions, resulting in a two-dimensional network.

AB - The asymmetric unit of the crystal structure of the title compound, C 14H15NO2S, contains two mol-ecules. The conformations of the N - C bonds in the C - SO2 - NH - C segments of the structure have trans and gauche torsion angles with the S=O bonds. Furthermore, the torsion angles of the C - SO2 - NH - C groups in the two mol-ecules are 46.1 (3) (glide image of mol-ecule 1) and 47.7 (3)° (mol-ecule 2). The ortho-methyl groups in the sulfonyl benzene ring are oriented away from the S=O bonds. The two benzene rings are tilted relative to each other by 67.5 (1) and 72.9 (1)° in the two mol-ecules. N - H⋯O and C - H⋯O hydrogen bonds pack the mol-ecules into one-dimensional chains in different directions, resulting in a two-dimensional network.

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