5-[4′-(Bromomethyl)biphenyl-2-yl]-2-trityl-2H-tetrazole

Basavegowda Nagaraj, Rajenahally S. Narasegowda, Hemmige S. Yathirajan, Santhosh L. Gaonkar, Michael Bolte

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

The synthesis of 5-[4′-(Bromomethyl)biphenyl-2-yl]-2-trityl-2H-tetrazole, was studied. The 5-(4′-Methylbiphenyl-2-yl)-1H-tetrezole, trityl chloride and triethylamine in dichloromethane were stirred for 2 hours at room temperature. To obtain the compound the recovered product was treated with 1-bromo2,5-pyrrolidinedione and benzoyal peroxide in carbon tetrachloride. It is observed that the compound 5-[4′-(Bromomethyl)biphenyl-2-yl]-2-trityl-2H-tetrazole is recrystallized from ethyl methyl ketone.

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume61
Issue number3
DOIs
Publication statusPublished - 03-2005

Fingerprint

tetrazoles
Carbon tetrachloride
Dichloromethane
Peroxides
Ketones
Succinimides
Carbon Tetrachloride
Methylene Chloride
carbon tetrachloride
peroxides
ketones
chlorides
Temperature
room temperature
synthesis
products
1H-tetrazole
diphenyl
triethylamine
trityl chloride

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

Nagaraj, Basavegowda ; Narasegowda, Rajenahally S. ; Yathirajan, Hemmige S. ; Gaonkar, Santhosh L. ; Bolte, Michael. / 5-[4′-(Bromomethyl)biphenyl-2-yl]-2-trityl-2H-tetrazole. In: Acta Crystallographica Section E: Structure Reports Online. 2005 ; Vol. 61, No. 3.
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abstract = "The synthesis of 5-[4′-(Bromomethyl)biphenyl-2-yl]-2-trityl-2H-tetrazole, was studied. The 5-(4′-Methylbiphenyl-2-yl)-1H-tetrezole, trityl chloride and triethylamine in dichloromethane were stirred for 2 hours at room temperature. To obtain the compound the recovered product was treated with 1-bromo2,5-pyrrolidinedione and benzoyal peroxide in carbon tetrachloride. It is observed that the compound 5-[4′-(Bromomethyl)biphenyl-2-yl]-2-trityl-2H-tetrazole is recrystallized from ethyl methyl ketone.",
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5-[4′-(Bromomethyl)biphenyl-2-yl]-2-trityl-2H-tetrazole. / Nagaraj, Basavegowda; Narasegowda, Rajenahally S.; Yathirajan, Hemmige S.; Gaonkar, Santhosh L.; Bolte, Michael.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 61, No. 3, 03.2005.

Research output: Contribution to journalArticle

TY - JOUR

T1 - 5-[4′-(Bromomethyl)biphenyl-2-yl]-2-trityl-2H-tetrazole

AU - Nagaraj, Basavegowda

AU - Narasegowda, Rajenahally S.

AU - Yathirajan, Hemmige S.

AU - Gaonkar, Santhosh L.

AU - Bolte, Michael

PY - 2005/3

Y1 - 2005/3

N2 - The synthesis of 5-[4′-(Bromomethyl)biphenyl-2-yl]-2-trityl-2H-tetrazole, was studied. The 5-(4′-Methylbiphenyl-2-yl)-1H-tetrezole, trityl chloride and triethylamine in dichloromethane were stirred for 2 hours at room temperature. To obtain the compound the recovered product was treated with 1-bromo2,5-pyrrolidinedione and benzoyal peroxide in carbon tetrachloride. It is observed that the compound 5-[4′-(Bromomethyl)biphenyl-2-yl]-2-trityl-2H-tetrazole is recrystallized from ethyl methyl ketone.

AB - The synthesis of 5-[4′-(Bromomethyl)biphenyl-2-yl]-2-trityl-2H-tetrazole, was studied. The 5-(4′-Methylbiphenyl-2-yl)-1H-tetrezole, trityl chloride and triethylamine in dichloromethane were stirred for 2 hours at room temperature. To obtain the compound the recovered product was treated with 1-bromo2,5-pyrrolidinedione and benzoyal peroxide in carbon tetrachloride. It is observed that the compound 5-[4′-(Bromomethyl)biphenyl-2-yl]-2-trityl-2H-tetrazole is recrystallized from ethyl methyl ketone.

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