A convenient synthesis of Fe(CO)22-S2CNMe2)2 and Fe(η2-S2CNMe2)2 from the monodentate dithiocarbamato derivative, [(η5-C5H5)(CO)3W(η1-SCSNMe2)] and Fe2(CO)9

Salil K. Jha, B. H.S. Thimmappa, Pradeep Mathur

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6 Citations (Scopus)


A high yield synthesis of the carbonyl dithiocarbamato derivative Fe(CO)22-S2CNMe2)2 and Fe(η2-S2CNMe2)2 by photolysis with visible light of solutions containing Fe2(CO)9 or Fe3(CO)12 and [(η5-C5H5)(CO)3W(η1-SCSNMe2)] is reported.

Original languageEnglish
Pages (from-to)2123-2125
Number of pages3
Issue number12
Publication statusPublished - 01-01-1986

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry


Dive into the research topics of 'A convenient synthesis of Fe(CO)<sub>2</sub>(η<sup>2</sup>-S<sub>2</sub>CNMe<sub>2</sub>)<sub>2</sub> and Fe(η<sup>2</sup>-S<sub>2</sub>CNMe<sub>2</sub>)<sub>2</sub> from the monodentate dithiocarbamato derivative, [(η<sup>5</sup>-C<sub>5</sub>H<sub>5</sub>)(CO)<sub>3</sub>W(η<sup>1</sup>-SCSNMe<sub>2</sub>)] and Fe<sub>2</sub>(CO)<sub>9</sub>'. Together they form a unique fingerprint.

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