A new chitosan biopolymer derivative for the removal of copper (II) and lead (II) from aqueous solutions: Synthesis, characterization and adsorption studies

K. Balakrishna Prabhu, M. B. Saidutta, Arun M. Isloor, Girish Kamath

Research output: Contribution to journalArticle

Abstract

A new chitosan derivative was prepared by grafting a ligand [3-(4methoxyphenyl)-1H-pyrazole-4-carbaldehyde] to chitosan by a Schiff base reaction. The chitosan-ligand derivative (CTSL) was characterized by spectral studies (FT-IR,13C NMR, XRD) and scanning electronic microscope. The suitability of CTSL as an adsorbent for the removal of two metals viz. Cu (II) and Pb (II) was studied by conducting equilibrium, kinetic and thermodynamic studies. Experimental data obtained in equilibrium studies were analyzed for Langmuir, Freundlich, and Redlich-Peterson isotherms. The maximum monolayer adsorption capacity obtained for the two metals were CTSL-Cu (40.62 mg/g) and CTSL-Pb (71.99 mg/g). The data obtained from the kinetic study was analyzed with three models viz. pseudo-first order, pseudo-second order and intraparticle diffusion models. The pseudo-second-order rate equation fitted the experimental data very well. Thermodynamic parameters ΔG, ΔH and ΔS were determined. The sorption operation was feasible, exothermic and accompanied with a positive increase in entropy. The metal interactions with the adsorbent were attributed to the hydroxyl, imine and the amine groups present in the synthesized derivative.

Original languageEnglish
Pages (from-to)1-9
Number of pages9
JournalJurnal Teknologi
Volume79
Issue number6
DOIs
Publication statusPublished - 01-09-2017
Externally publishedYes

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Biopolymers
Chitosan
Lead
Derivatives
Copper
Adsorption
Ligands
Adsorbents
Metals
Thermodynamics
Kinetics
Isotherms
Sorption
Amines
Monolayers
Microscopes
Entropy
Nuclear magnetic resonance
Scanning

All Science Journal Classification (ASJC) codes

  • Engineering(all)

Cite this

Prabhu, K. Balakrishna ; Saidutta, M. B. ; Isloor, Arun M. ; Kamath, Girish. / A new chitosan biopolymer derivative for the removal of copper (II) and lead (II) from aqueous solutions : Synthesis, characterization and adsorption studies. In: Jurnal Teknologi. 2017 ; Vol. 79, No. 6. pp. 1-9.
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A new chitosan biopolymer derivative for the removal of copper (II) and lead (II) from aqueous solutions : Synthesis, characterization and adsorption studies. / Prabhu, K. Balakrishna; Saidutta, M. B.; Isloor, Arun M.; Kamath, Girish.

In: Jurnal Teknologi, Vol. 79, No. 6, 01.09.2017, p. 1-9.

Research output: Contribution to journalArticle

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AU - Kamath, Girish

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