A new method for the generation of α-nitrosoolefins from ketooximes and its application to the synthesis of 5,6-dihydro-4H-1,2-oxazine derivatives [1]

S. L. Gaonkar, K. M.Lokanatha Rai

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

Reaction of ketooximes containing α-methylene group with chloramine-T followed by treatment with triethylamine leads to the formation of α-nitrosoolefins via α-nitrosochloride, which can react in situ intermolecularly with olefinic compounds to produce 5,6-dihydro-4H-1,2-oxazine derivatives in good yield.

Original languageEnglish
Pages (from-to)877-881
Number of pages5
JournalJournal of Heterocyclic Chemistry
Volume42
Issue number5
Publication statusPublished - 07-2005

All Science Journal Classification (ASJC) codes

  • Organic Chemistry

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