Biodegradability of PMMA blends with some cellulose derivatives

Denthaje Krishna Bhat, M. Selva Kumar

Research output: Contribution to journalArticle

29 Citations (Scopus)

Abstract

High polymer blends of Polymethyl methacrylate (PMMA) with cellulose acetate (CA) and Cellulose acetate phthalate (CAP) of varying blend compositions have been prepared to study their biodegradation behavior and blend miscibility. Films of PMMA-CA, and PMMA-CAP blends have been prepared by solution casting using Acetone and Dimethyl formamide(DMF) as solvents respectively. Biodegradability of these blends has been studied by four different methods namely, soil burial test, enzymatic degradation, and degradation in phosphate buffer and activated sludge degradation followed by water absorption tests to support the degradation studies. Degradation analysis was done by weight loss method. The results of all the tests showed sufficient biodegradability of these blends. Degradability increased with the increase in CA and CAP content in the blend compositions. The miscibility of PMMA-CA and PMMA-CAP blends have been studied by solution viscometric and ultrasonic methods. The results obtained reveal that PMMA forms miscible blends with either CA or CAP in the entire composition range. Miscibility of the blends may be due to the formation of hydrogen bond between the carbonyl group of PMMA and the free hydroxyl group of CA and CAP.

Original languageEnglish
Pages (from-to)385-392
Number of pages8
JournalJournal of Polymers and the Environment
Volume14
Issue number4
DOIs
Publication statusPublished - 01-10-2006

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Cellulose derivatives
Biodegradability
Polymethyl Methacrylate
Polymethyl methacrylates
Cellulose
Degradation
Solubility
Chemical analysis
Dimethylformamide
Water absorption
Polymer blends
Acetone
Biodegradation
Hydroxyl Radical
acetylcellulose
cellulose acetate phthalate
Hydrogen bonds
Buffers
Casting
Ultrasonics

All Science Journal Classification (ASJC) codes

  • Environmental Engineering
  • Polymers and Plastics
  • Materials Chemistry

Cite this

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abstract = "High polymer blends of Polymethyl methacrylate (PMMA) with cellulose acetate (CA) and Cellulose acetate phthalate (CAP) of varying blend compositions have been prepared to study their biodegradation behavior and blend miscibility. Films of PMMA-CA, and PMMA-CAP blends have been prepared by solution casting using Acetone and Dimethyl formamide(DMF) as solvents respectively. Biodegradability of these blends has been studied by four different methods namely, soil burial test, enzymatic degradation, and degradation in phosphate buffer and activated sludge degradation followed by water absorption tests to support the degradation studies. Degradation analysis was done by weight loss method. The results of all the tests showed sufficient biodegradability of these blends. Degradability increased with the increase in CA and CAP content in the blend compositions. The miscibility of PMMA-CA and PMMA-CAP blends have been studied by solution viscometric and ultrasonic methods. The results obtained reveal that PMMA forms miscible blends with either CA or CAP in the entire composition range. Miscibility of the blends may be due to the formation of hydrogen bond between the carbonyl group of PMMA and the free hydroxyl group of CA and CAP.",
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Biodegradability of PMMA blends with some cellulose derivatives. / Bhat, Denthaje Krishna; Kumar, M. Selva.

In: Journal of Polymers and the Environment, Vol. 14, No. 4, 01.10.2006, p. 385-392.

Research output: Contribution to journalArticle

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