Catalytic etherification of glycerol to tert-butyl glycerol ethers using tert -butanol over sulfonic acid functionalized mesoporous polymer

Pandian Manjunathan; Manish Kumar; Sathyapal R. Churipard; S. Sivasankaran; Ganapati V. Shanbhag; Sanjeev P. Maradur

doi:10.1039/c6ra18609b

Catalytic etherification of glycerol to tert-butyl glycerol ethers using tert -butanol over sulfonic acid functionalized mesoporous polymer

Pandian Manjunathan, Manish Kumar, Sathyapal R. Churipard, S. Sivasankaran, Ganapati V. Shanbhag, Sanjeev P. Maradur

Research output: Contribution to journal › Article

15 Citations (Scopus)

Abstract

Mesoporous polymers (MP) were synthesized by free radical polymerization of divinylbenzene by a solvothermal method followed by sulfonic acid functionalization by a post synthetic modification with conc. H₂SO₄. MP-SO₃H was characterized by various physicochemical techniques such as FT-IR, nitrogen sorption, CHNS analysis, acid-base titration and TGA. MP-SO₃H was demonstrated to be a highly active heterogeneous acid catalyst, providing a high yielding route for the synthesis of h-GTBE through the etherification of bio-renewable glycerol with tert-butanol. MP-SO₃H containing optimum acidity and a large mesoporous surface area gave 44% h-GTBE selectivity at 86% glycerol conversion under optimized reaction conditions. The catalytic performance of MP-SO₃H was found to be superior over other conventional porous solid acid catalysts.

Original language	English
Pages (from-to)	82654-82660
Number of pages	7
Journal	RSC Advances
Volume	6
Issue number	86
DOIs	https://doi.org/10.1039/c6ra18609b
Publication status	Published - 01-01-2016
Externally published	Yes

All Science Journal Classification (ASJC) codes

Chemistry(all)
Chemical Engineering(all)

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10.1039/c6ra18609b

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Manjunathan, P., Kumar, M., Churipard, S. R., Sivasankaran, S., Shanbhag, G. V., & Maradur, S. P. (2016). Catalytic etherification of glycerol to tert-butyl glycerol ethers using tert -butanol over sulfonic acid functionalized mesoporous polymer. RSC Advances, 6(86), 82654-82660. https://doi.org/10.1039/c6ra18609b

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abstract = "Mesoporous polymers (MP) were synthesized by free radical polymerization of divinylbenzene by a solvothermal method followed by sulfonic acid functionalization by a post synthetic modification with conc. H2SO4. MP-SO3H was characterized by various physicochemical techniques such as FT-IR, nitrogen sorption, CHNS analysis, acid-base titration and TGA. MP-SO3H was demonstrated to be a highly active heterogeneous acid catalyst, providing a high yielding route for the synthesis of h-GTBE through the etherification of bio-renewable glycerol with tert-butanol. MP-SO3H containing optimum acidity and a large mesoporous surface area gave 44% h-GTBE selectivity at 86% glycerol conversion under optimized reaction conditions. The catalytic performance of MP-SO3H was found to be superior over other conventional porous solid acid catalysts.",

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Catalytic etherification of glycerol to tert-butyl glycerol ethers using tert -butanol over sulfonic acid functionalized mesoporous polymer. / Manjunathan, Pandian; Kumar, Manish; Churipard, Sathyapal R.; Sivasankaran, S.; Shanbhag, Ganapati V.; Maradur, Sanjeev P.

In: RSC Advances, Vol. 6, No. 86, 01.01.2016, p. 82654-82660.

Research output: Contribution to journal › Article

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AU - Manjunathan, Pandian

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AU - Shanbhag, Ganapati V.

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