Catena-Poly[[(ethanol-O)[3-(1-phenyl-1H-pyrazol-3-yl)benzoic acid-O]lithium] - 3-(1-phenyl-1H-pyrazol-3-yl)benzoato-2 O

O′]

Hoong Kun Fun, Kasthuri Balasubramani, Sankappa Rai, Prakash Shetty, Arun M. Isloor

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

The asymmetric unit of the title polymeric compound, [Li2(C 16H11N2O2)2(C 16H12N2O2)2(CH 3CH2OH)2] n , contains two Li I ions, two 3-(1-phenyl-1H-pyrazol-3-yl)benzoate ions, two 3-(1-phenyl-1H-pyrazol-3-yl)benzoic acid molecules and two ethanol molecules. In the crystal structure, each of the two LiI ions has a distorted tetra-hedral geometry, coordinated by two carboxyl-ate O atoms, one carboxyl O atom and one ethanol O atom. The carboxyl-ate group bridges the LiI ions, forming a one-dimensional polymeric chain along [100]. The crystal structure is further stabilized by O - H⋯O and C - H⋯N hydrogen bonding, and π-π inter-actions with centroid-centroid distances in the range 3.6534 (13)-3.8374 (13) Å.

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume65
Issue number8
DOIs
Publication statusPublished - 20-08-2009

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Benzoic Acid
Benzoic acid
benzoic acid
Lithium
Ethanol
ethyl alcohol
lithium
Ions
Atoms
centroids
ions
Crystal structure
atoms
crystal structure
Molecules
Benzoates
carboxyl group
molecules
Hydrogen bonds
methylidyne

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

@article{98e59e05210c4c1f8e2ebfaa05a53c9e,
title = "Catena-Poly[[(ethanol-O)[3-(1-phenyl-1H-pyrazol-3-yl)benzoic acid-O]lithium] - 3-(1-phenyl-1H-pyrazol-3-yl)benzoato-2 O: O′]",
abstract = "The asymmetric unit of the title polymeric compound, [Li2(C 16H11N2O2)2(C 16H12N2O2)2(CH 3CH2OH)2] n , contains two Li I ions, two 3-(1-phenyl-1H-pyrazol-3-yl)benzoate ions, two 3-(1-phenyl-1H-pyrazol-3-yl)benzoic acid molecules and two ethanol molecules. In the crystal structure, each of the two LiI ions has a distorted tetra-hedral geometry, coordinated by two carboxyl-ate O atoms, one carboxyl O atom and one ethanol O atom. The carboxyl-ate group bridges the LiI ions, forming a one-dimensional polymeric chain along [100]. The crystal structure is further stabilized by O - H⋯O and C - H⋯N hydrogen bonding, and π-π inter-actions with centroid-centroid distances in the range 3.6534 (13)-3.8374 (13) {\AA}.",
author = "Fun, {Hoong Kun} and Kasthuri Balasubramani and Sankappa Rai and Prakash Shetty and Isloor, {Arun M.}",
year = "2009",
month = "8",
day = "20",
doi = "10.1107/S1600536809026385",
language = "English",
volume = "65",
journal = "Acta Crystallographica Section E: Structure Reports Online",
issn = "1600-5368",
publisher = "International Union of Crystallography",
number = "8",

}

Catena-Poly[[(ethanol-O)[3-(1-phenyl-1H-pyrazol-3-yl)benzoic acid-O]lithium] - 3-(1-phenyl-1H-pyrazol-3-yl)benzoato-2 O : O′]. / Fun, Hoong Kun; Balasubramani, Kasthuri; Rai, Sankappa; Shetty, Prakash; Isloor, Arun M.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 65, No. 8, 20.08.2009.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Catena-Poly[[(ethanol-O)[3-(1-phenyl-1H-pyrazol-3-yl)benzoic acid-O]lithium] - 3-(1-phenyl-1H-pyrazol-3-yl)benzoato-2 O

T2 - O′]

AU - Fun, Hoong Kun

AU - Balasubramani, Kasthuri

AU - Rai, Sankappa

AU - Shetty, Prakash

AU - Isloor, Arun M.

PY - 2009/8/20

Y1 - 2009/8/20

N2 - The asymmetric unit of the title polymeric compound, [Li2(C 16H11N2O2)2(C 16H12N2O2)2(CH 3CH2OH)2] n , contains two Li I ions, two 3-(1-phenyl-1H-pyrazol-3-yl)benzoate ions, two 3-(1-phenyl-1H-pyrazol-3-yl)benzoic acid molecules and two ethanol molecules. In the crystal structure, each of the two LiI ions has a distorted tetra-hedral geometry, coordinated by two carboxyl-ate O atoms, one carboxyl O atom and one ethanol O atom. The carboxyl-ate group bridges the LiI ions, forming a one-dimensional polymeric chain along [100]. The crystal structure is further stabilized by O - H⋯O and C - H⋯N hydrogen bonding, and π-π inter-actions with centroid-centroid distances in the range 3.6534 (13)-3.8374 (13) Å.

AB - The asymmetric unit of the title polymeric compound, [Li2(C 16H11N2O2)2(C 16H12N2O2)2(CH 3CH2OH)2] n , contains two Li I ions, two 3-(1-phenyl-1H-pyrazol-3-yl)benzoate ions, two 3-(1-phenyl-1H-pyrazol-3-yl)benzoic acid molecules and two ethanol molecules. In the crystal structure, each of the two LiI ions has a distorted tetra-hedral geometry, coordinated by two carboxyl-ate O atoms, one carboxyl O atom and one ethanol O atom. The carboxyl-ate group bridges the LiI ions, forming a one-dimensional polymeric chain along [100]. The crystal structure is further stabilized by O - H⋯O and C - H⋯N hydrogen bonding, and π-π inter-actions with centroid-centroid distances in the range 3.6534 (13)-3.8374 (13) Å.

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