Complexometric determination of thallium(III) using ethanethiol as a selective masking agent

J. Karthikeyan, P. Parameshwara, A. Nityananda Shetty, Prakash Shetty

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

A simple and selective complexometric method for the determination of thallium in presence of other metal ions is proposed based on the selective masking ability of ethanethiol towards thallium(III). Thallium present in a given sample solution is first complexed with a known excess of EDTA and the surplus EDTA is titrated with standard zinc sulphate solution at pH 5-6(hexamine) using xylenol orange as the indicator. A 0.3% aqueous solution of ethanethiol is then added to displace EDTA from the Tl(III)-EDTA complex. The released EDTA is titrated with standard zinc sulphate solution as before. Reproducible and accurate results are obtained for 3.70 mg to 74.07 mg of Tl (III) with relative error less than ±0.44% and coefficient of variation not more than 0.27%. The interference of various ions was studied and the method was used for the analysis of thallium in its synthetic alloy mixtures and also in complexes.

Original languageEnglish
Pages (from-to)316-320
Number of pages5
JournalJournal of the Brazilian Chemical Society
Volume17
Issue number2
DOIs
Publication statusPublished - 01-01-2006

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Thallium
Edetic Acid
Zinc Sulfate
Methenamine
Metal ions
ethanethiol
Ions

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

Cite this

Karthikeyan, J. ; Parameshwara, P. ; Nityananda Shetty, A. ; Shetty, Prakash. / Complexometric determination of thallium(III) using ethanethiol as a selective masking agent. In: Journal of the Brazilian Chemical Society. 2006 ; Vol. 17, No. 2. pp. 316-320.
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abstract = "A simple and selective complexometric method for the determination of thallium in presence of other metal ions is proposed based on the selective masking ability of ethanethiol towards thallium(III). Thallium present in a given sample solution is first complexed with a known excess of EDTA and the surplus EDTA is titrated with standard zinc sulphate solution at pH 5-6(hexamine) using xylenol orange as the indicator. A 0.3{\%} aqueous solution of ethanethiol is then added to displace EDTA from the Tl(III)-EDTA complex. The released EDTA is titrated with standard zinc sulphate solution as before. Reproducible and accurate results are obtained for 3.70 mg to 74.07 mg of Tl (III) with relative error less than ±0.44{\%} and coefficient of variation not more than 0.27{\%}. The interference of various ions was studied and the method was used for the analysis of thallium in its synthetic alloy mixtures and also in complexes.",
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Complexometric determination of thallium(III) using ethanethiol as a selective masking agent. / Karthikeyan, J.; Parameshwara, P.; Nityananda Shetty, A.; Shetty, Prakash.

In: Journal of the Brazilian Chemical Society, Vol. 17, No. 2, 01.01.2006, p. 316-320.

Research output: Contribution to journalArticle

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