Corrosion inhibition of 6061 aluminium alloy/SiCp composite in hydrochloric acid medium using 3-chloro-1-benzothiophene-2-carbohydrazide

U. Achutha Kini, Prakash Shetty, S. Divakara Shetty, M. Arun Isloor

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

The inhibitive action of 3-chloro-1-benzothiophene-2-carbohydrazide (CBTC) on the corrosion behavior of 6061 Al alloy/SiCp composite has been studied at four different temperatures (30°, 40°, 50° and 60°C) in hydrochloric acid medium (0.5 and 1 M) using Tafel extrapolation technique and weight loss method. Polarization curves indicate that CBTC acts as cathodic inhibitor. Inhibition efficiency is found to increase with increasing inhibitor concentration upto a critical value and with decreasing temperature. The inhibition efficiencies obtained by Tafel extrapolation technique and weight loss method are in good agreement. The adsorption of the inhibitor on the composite surface is found to obey Temkins' and Langmuir adsorption isotherms. The inhibition is governed by physisorption mechanism.

Original languageEnglish
Pages (from-to)439-445
Number of pages7
JournalIndian Journal of Chemical Technology
Volume18
Issue number6
Publication statusPublished - 01-11-2011

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Hydrochloric Acid
Hydrochloric acid
Extrapolation
Aluminum alloys
Corrosion
Physisorption
Composite materials
Adsorption isotherms
Polarization
Adsorption
Temperature
carbohydrazide
benzothiophene

All Science Journal Classification (ASJC) codes

  • Chemical Engineering(all)
  • Chemistry(all)

Cite this

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title = "Corrosion inhibition of 6061 aluminium alloy/SiCp composite in hydrochloric acid medium using 3-chloro-1-benzothiophene-2-carbohydrazide",
abstract = "The inhibitive action of 3-chloro-1-benzothiophene-2-carbohydrazide (CBTC) on the corrosion behavior of 6061 Al alloy/SiCp composite has been studied at four different temperatures (30°, 40°, 50° and 60°C) in hydrochloric acid medium (0.5 and 1 M) using Tafel extrapolation technique and weight loss method. Polarization curves indicate that CBTC acts as cathodic inhibitor. Inhibition efficiency is found to increase with increasing inhibitor concentration upto a critical value and with decreasing temperature. The inhibition efficiencies obtained by Tafel extrapolation technique and weight loss method are in good agreement. The adsorption of the inhibitor on the composite surface is found to obey Temkins' and Langmuir adsorption isotherms. The inhibition is governed by physisorption mechanism.",
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Corrosion inhibition of 6061 aluminium alloy/SiCp composite in hydrochloric acid medium using 3-chloro-1-benzothiophene-2-carbohydrazide. / Achutha Kini, U.; Shetty, Prakash; Divakara Shetty, S.; Arun Isloor, M.

In: Indian Journal of Chemical Technology, Vol. 18, No. 6, 01.11.2011, p. 439-445.

Research output: Contribution to journalArticle

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AB - The inhibitive action of 3-chloro-1-benzothiophene-2-carbohydrazide (CBTC) on the corrosion behavior of 6061 Al alloy/SiCp composite has been studied at four different temperatures (30°, 40°, 50° and 60°C) in hydrochloric acid medium (0.5 and 1 M) using Tafel extrapolation technique and weight loss method. Polarization curves indicate that CBTC acts as cathodic inhibitor. Inhibition efficiency is found to increase with increasing inhibitor concentration upto a critical value and with decreasing temperature. The inhibition efficiencies obtained by Tafel extrapolation technique and weight loss method are in good agreement. The adsorption of the inhibitor on the composite surface is found to obey Temkins' and Langmuir adsorption isotherms. The inhibition is governed by physisorption mechanism.

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