Effect of sulfurization temperature on Cu-Zn disorder for non-stoichiometric spray pyrolyzed Cu2ZnSnS4 thin films

K. Jeganath; Sajan D. George; M. S. Murari; Y. Raviprakash

doi:10.1016/j.matlet.2021.130168

Effect of sulfurization temperature on Cu-Zn disorder for non-stoichiometric spray pyrolyzed Cu₂ZnSnS₄ thin films

K. Jeganath, Sajan D. George, M. S. Murari, Y. Raviprakash

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

Cu₂ZnSnS₄(CZTS) thin-films were synthesized using chemical spray pyrolysis technique followed by sulfurization at different temperatures via the chemical vapor deposition technique. The Cu-Zn disorder for the films sulfurized at various temperatures was investigated using the near-resonance Raman spectra with an excitation wavelength of 785 nm. The sulfurized films exhibited optimal non-stoichiometric Cu-poor and Zn- rich composition to achieve higher solar cell efficiency. The CZTS films sulfurized at a temperature of 550 °C exhibited higher Cu-Zn order.

Original language	English
Article number	130168
Journal	Materials Letters
Volume	300
DOIs	https://doi.org/10.1016/j.matlet.2021.130168
Publication status	Published - 01-10-2021

All Science Journal Classification (ASJC) codes

Materials Science(all)
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering

Access to Document

10.1016/j.matlet.2021.130168

Cite this

@article{cc2c1f4acdb94a24afd5678b5202183c,

title = "Effect of sulfurization temperature on Cu-Zn disorder for non-stoichiometric spray pyrolyzed Cu2ZnSnS4 thin films",

abstract = "Cu2ZnSnS4(CZTS) thin-films were synthesized using chemical spray pyrolysis technique followed by sulfurization at different temperatures via the chemical vapor deposition technique. The Cu-Zn disorder for the films sulfurized at various temperatures was investigated using the near-resonance Raman spectra with an excitation wavelength of 785 nm. The sulfurized films exhibited optimal non-stoichiometric Cu-poor and Zn- rich composition to achieve higher solar cell efficiency. The CZTS films sulfurized at a temperature of 550 °C exhibited higher Cu-Zn order.",

author = "K. Jeganath and George, {Sajan D.} and Murari, {M. S.} and Y. Raviprakash",

note = "Funding Information: This work was supported by the Department of Science and Technology (DST) under Science and Engineering Research Board (SERB), Govt. of India (EMR/2017/002575). Funding Information: This work was supported by the Department of Science and Technology (DST) under Science and Engineering Research Board (SERB) , Govt. of India ( EMR/2017/002575 ). Publisher Copyright: {\textcopyright} 2021 Elsevier B.V.",

year = "2021",

month = oct,

day = "1",

doi = "10.1016/j.matlet.2021.130168",

language = "English",

volume = "300",

journal = "Materials Letters",

issn = "0167-577X",

publisher = "Elsevier",

}

TY - JOUR

T1 - Effect of sulfurization temperature on Cu-Zn disorder for non-stoichiometric spray pyrolyzed Cu2ZnSnS4 thin films

AU - Jeganath, K.

AU - George, Sajan D.

AU - Murari, M. S.

AU - Raviprakash, Y.

N1 - Funding Information: This work was supported by the Department of Science and Technology (DST) under Science and Engineering Research Board (SERB), Govt. of India (EMR/2017/002575). Funding Information: This work was supported by the Department of Science and Technology (DST) under Science and Engineering Research Board (SERB) , Govt. of India ( EMR/2017/002575 ). Publisher Copyright: © 2021 Elsevier B.V.

PY - 2021/10/1

Y1 - 2021/10/1

N2 - Cu2ZnSnS4(CZTS) thin-films were synthesized using chemical spray pyrolysis technique followed by sulfurization at different temperatures via the chemical vapor deposition technique. The Cu-Zn disorder for the films sulfurized at various temperatures was investigated using the near-resonance Raman spectra with an excitation wavelength of 785 nm. The sulfurized films exhibited optimal non-stoichiometric Cu-poor and Zn- rich composition to achieve higher solar cell efficiency. The CZTS films sulfurized at a temperature of 550 °C exhibited higher Cu-Zn order.

AB - Cu2ZnSnS4(CZTS) thin-films were synthesized using chemical spray pyrolysis technique followed by sulfurization at different temperatures via the chemical vapor deposition technique. The Cu-Zn disorder for the films sulfurized at various temperatures was investigated using the near-resonance Raman spectra with an excitation wavelength of 785 nm. The sulfurized films exhibited optimal non-stoichiometric Cu-poor and Zn- rich composition to achieve higher solar cell efficiency. The CZTS films sulfurized at a temperature of 550 °C exhibited higher Cu-Zn order.

UR - http://www.scopus.com/inward/record.url?scp=85107648941&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85107648941&partnerID=8YFLogxK

U2 - 10.1016/j.matlet.2021.130168

DO - 10.1016/j.matlet.2021.130168

M3 - Article

AN - SCOPUS:85107648941

SN - 0167-577X

VL - 300

JO - Materials Letters

JF - Materials Letters

M1 - 130168

ER -

Effect of sulfurization temperature on Cu-Zn disorder for non-stoichiometric spray pyrolyzed Cu₂ZnSnS₄ thin films

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this