Electrochemical measurements for the corrosion inhibition of mild steel in 1 M hydrochloric acid by using an aromatic hydrazide derivative

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Abstract

The influence of an aromatic hydrazide derivative, 2-(3,4,5-trimethoxybenzylidene) hydrazinecarbothioamide (TMBHC) as corrosion inhibitor on mild steel in 1 M hydrochloric acid was studied by Tafel polarization and electrochemical impedance spectroscopy (EIS) technique. The results showed that the inhibition efficiency (% IE) of TMBHC increased with increasing inhibitor concentrations and also with increase in temperatures. TMBHC acted as a mixed type of inhibitor and its adsorption on mild steel surface was found to follow Langmuir's adsorption isotherm. The evaluation of thermodynamic and activation parameters indicated that the adsorption of TMBHC takes place through chemisorption. The formation of protective film was further confirmed by scanning electron microscopy (SEM).

Original languageEnglish
Pages (from-to)653-663
Number of pages11
JournalArabian Journal of Chemistry
Volume10
Issue number5
DOIs
Publication statusPublished - 01-07-2017

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Hydrochloric Acid
Hydrochloric acid
Carbon steel
Corrosion
Derivatives
Adsorption
Protective coatings
Corrosion inhibitors
Chemisorption
Electrochemical impedance spectroscopy
Adsorption isotherms
Chemical activation
Thermodynamics
Polarization
Scanning electron microscopy
Temperature

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Chemical Engineering(all)

Cite this

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title = "Electrochemical measurements for the corrosion inhibition of mild steel in 1 M hydrochloric acid by using an aromatic hydrazide derivative",
abstract = "The influence of an aromatic hydrazide derivative, 2-(3,4,5-trimethoxybenzylidene) hydrazinecarbothioamide (TMBHC) as corrosion inhibitor on mild steel in 1 M hydrochloric acid was studied by Tafel polarization and electrochemical impedance spectroscopy (EIS) technique. The results showed that the inhibition efficiency ({\%} IE) of TMBHC increased with increasing inhibitor concentrations and also with increase in temperatures. TMBHC acted as a mixed type of inhibitor and its adsorption on mild steel surface was found to follow Langmuir's adsorption isotherm. The evaluation of thermodynamic and activation parameters indicated that the adsorption of TMBHC takes place through chemisorption. The formation of protective film was further confirmed by scanning electron microscopy (SEM).",
author = "{Preethi Kumari}, P. and Prakash Shetty and Rao, {Suma A.}",
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T1 - Electrochemical measurements for the corrosion inhibition of mild steel in 1 M hydrochloric acid by using an aromatic hydrazide derivative

AU - Preethi Kumari, P.

AU - Shetty, Prakash

AU - Rao, Suma A.

PY - 2017/7/1

Y1 - 2017/7/1

N2 - The influence of an aromatic hydrazide derivative, 2-(3,4,5-trimethoxybenzylidene) hydrazinecarbothioamide (TMBHC) as corrosion inhibitor on mild steel in 1 M hydrochloric acid was studied by Tafel polarization and electrochemical impedance spectroscopy (EIS) technique. The results showed that the inhibition efficiency (% IE) of TMBHC increased with increasing inhibitor concentrations and also with increase in temperatures. TMBHC acted as a mixed type of inhibitor and its adsorption on mild steel surface was found to follow Langmuir's adsorption isotherm. The evaluation of thermodynamic and activation parameters indicated that the adsorption of TMBHC takes place through chemisorption. The formation of protective film was further confirmed by scanning electron microscopy (SEM).

AB - The influence of an aromatic hydrazide derivative, 2-(3,4,5-trimethoxybenzylidene) hydrazinecarbothioamide (TMBHC) as corrosion inhibitor on mild steel in 1 M hydrochloric acid was studied by Tafel polarization and electrochemical impedance spectroscopy (EIS) technique. The results showed that the inhibition efficiency (% IE) of TMBHC increased with increasing inhibitor concentrations and also with increase in temperatures. TMBHC acted as a mixed type of inhibitor and its adsorption on mild steel surface was found to follow Langmuir's adsorption isotherm. The evaluation of thermodynamic and activation parameters indicated that the adsorption of TMBHC takes place through chemisorption. The formation of protective film was further confirmed by scanning electron microscopy (SEM).

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