Four ring achiral ferroelectric liquid crystals of 1,2,4-oxadiazoles: synthesis and characterisation

Mahabaleshwara Subrao, Poornima Bhagavath, Sangeetha G. Bhat, Girish Sharada Ramachandra, D. M. Potukuchi, Srinivasulu Maddasani

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

A novel series of four-ring achiral ferroelectric liquid crystals containing 1,2,4-oxadiazole cores with unsymmetrical substitutions at C-3 and C-5 positions are synthesised and characterised. A fluoro substituted biphenyl moiety is prepared by Suzuki coupling reaction and is directly attached to the oxadiazole core at the C-5 position for the first time in the literature. An octyl benzoate is attached to the oxadiazole core at the C-3 position of it. All the compounds exhibit polar smectic (B2) mesophases with ferroelectric switching along with the orthogonal smectic-A mesophases. These compounds possess high mesomorphic thermal ranges of polar smectic phases and are towards the ambient temperatures. The influence of a more electronegative fluorine substituent on the electron rich biphenyl moiety (at the C-5 position) of the oxadiazole core is analysed for the prevalence and abundance of polar smectic (ferroelectric) mesophases.

Original languageEnglish
Pages (from-to)400-410
Number of pages11
JournalLiquid Crystals
Volume43
Issue number3
DOIs
Publication statusPublished - 19-02-2016

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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