Liquid-liquid equilibrium of poly(ethylene glycol) 6000 + sodium succinate + water system at different temperatures

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Abstract

Phase diagrams and the compositions of coexisting phases of poly(ethylene glycol) (PEG) 6000 + sodium succinate + water system have been determined experimentally at 298.15, 308.15, and 318.15 K. The effects of temperature on the binodal curve and tie lines have been studied. The binodal curves were successfully fitted to a nonlinear equation relating the concentrations of PEG 6000 and sodium succinate, and the coefficients were estimated for the formentioned systems (low AARD, high R2, and low SD). Tie-line compositions were estimated and correlated using Othmer-Tobias and Bancroft equations, and the parameters were reported. The effect of temperature on the phase-forming ability has been studied by fitting the binodal data to a Setschenow-type equation for each temperature. The effective excluded volume (EEV) values were also calculated from the binodal data, and it was found out that the values increased with an increase in the temperature. Furthermore, the effect of MW of PEG on the phase diagram has been studied and verified.

Original languageEnglish
Article number819259
JournalThe Scientific World Journal
Volume2013
DOIs
Publication statusPublished - 19-07-2013

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Ethylene Glycol
Succinic Acid
ethylene
Polyethylene glycols
Sodium
sodium
liquid
Temperature
Water
Liquids
Phase diagrams
temperature
diagram
water
Chemical analysis
Nonlinear equations
effect
Polyethylene Glycol 6000

All Science Journal Classification (ASJC) codes

  • Medicine(all)
  • Biochemistry, Genetics and Molecular Biology(all)
  • Environmental Science(all)

Cite this

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title = "Liquid-liquid equilibrium of poly(ethylene glycol) 6000 + sodium succinate + water system at different temperatures",
abstract = "Phase diagrams and the compositions of coexisting phases of poly(ethylene glycol) (PEG) 6000 + sodium succinate + water system have been determined experimentally at 298.15, 308.15, and 318.15 K. The effects of temperature on the binodal curve and tie lines have been studied. The binodal curves were successfully fitted to a nonlinear equation relating the concentrations of PEG 6000 and sodium succinate, and the coefficients were estimated for the formentioned systems (low AARD, high R2, and low SD). Tie-line compositions were estimated and correlated using Othmer-Tobias and Bancroft equations, and the parameters were reported. The effect of temperature on the phase-forming ability has been studied by fitting the binodal data to a Setschenow-type equation for each temperature. The effective excluded volume (EEV) values were also calculated from the binodal data, and it was found out that the values increased with an increase in the temperature. Furthermore, the effect of MW of PEG on the phase diagram has been studied and verified.",
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publisher = "Hindawi Publishing Corporation",

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AU - Raja, Selvaraj

AU - Murty, Vytla Ramachandra

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N2 - Phase diagrams and the compositions of coexisting phases of poly(ethylene glycol) (PEG) 6000 + sodium succinate + water system have been determined experimentally at 298.15, 308.15, and 318.15 K. The effects of temperature on the binodal curve and tie lines have been studied. The binodal curves were successfully fitted to a nonlinear equation relating the concentrations of PEG 6000 and sodium succinate, and the coefficients were estimated for the formentioned systems (low AARD, high R2, and low SD). Tie-line compositions were estimated and correlated using Othmer-Tobias and Bancroft equations, and the parameters were reported. The effect of temperature on the phase-forming ability has been studied by fitting the binodal data to a Setschenow-type equation for each temperature. The effective excluded volume (EEV) values were also calculated from the binodal data, and it was found out that the values increased with an increase in the temperature. Furthermore, the effect of MW of PEG on the phase diagram has been studied and verified.

AB - Phase diagrams and the compositions of coexisting phases of poly(ethylene glycol) (PEG) 6000 + sodium succinate + water system have been determined experimentally at 298.15, 308.15, and 318.15 K. The effects of temperature on the binodal curve and tie lines have been studied. The binodal curves were successfully fitted to a nonlinear equation relating the concentrations of PEG 6000 and sodium succinate, and the coefficients were estimated for the formentioned systems (low AARD, high R2, and low SD). Tie-line compositions were estimated and correlated using Othmer-Tobias and Bancroft equations, and the parameters were reported. The effect of temperature on the phase-forming ability has been studied by fitting the binodal data to a Setschenow-type equation for each temperature. The effective excluded volume (EEV) values were also calculated from the binodal data, and it was found out that the values increased with an increase in the temperature. Furthermore, the effect of MW of PEG on the phase diagram has been studied and verified.

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