Methyl 2,6-bis-[(5-chloro-4,6-dimethoxypyrimidin-2-yl)oxy]benzoate

Hoong Kun Fun, Jia Hao Goh, Sankappa Rai, Arun M. Isloor, Prakash Shetty

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

In the title compound, C20H18Cl2N 4O8, the two pyrimidine rings are inclined at dihedral angles of 66.68 (5) and 71.91 (6)° with respect to the central benzene ring. In the crystal structure, inter-molecular C-H⋯N hydrogen bonds link neighbouring molecules into a ribbon-like structure along the b axis. The ribbons are inter-connected into a two-dimensional network parallel to the bc plane by short inter-molecular Cl⋯Cl [3.4427 (6) Å] and Cl⋯O [3.1420 (9) and 3.1750 (11) Å] inter-actions. The crystal structure is further stabilized by inter-molecular π-π inter-actions [centroid-centroid distance 3.4552 (8) Å] involving the pyrimidine rings.

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume66
Issue number7
DOIs
Publication statusPublished - 14-07-2010

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All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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