Oxomolybdenum(V) complexes of 2-benzothiazolyl hydrazones

Sharada R. Girish, Vidyanand K. Revankar, Vinayak B. Mahale

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

Oxomolybdenum(V) complexes of general formulae [Mo2O3L2Cl2]H2O and [Mo2O3L2(OH)2(H2O) 2] (LH = hydrazones derived from 2-hydrazinobenzothiazole with salicyladehyde, 5-methyl-, 5-chloro-, 5-bromo-, 3-methoxysalicyldehyde and 2-hydroxy-1-naphthaldehyde) have been prepared and characterized by elemental analysis, conductivities, magnetic moments, thermal studies, and i.r., u.v.-vis. and e.p.r. spectra. The data suggest that the complexes are non-electrolytes, paramagnetic and have distorted octahedral structures with possible metal-metal interactions via oxo bridging.

Original languageEnglish
Pages (from-to)401-405
Number of pages5
JournalTransition Metal Chemistry
Volume21
Issue number5
Publication statusPublished - 10-1996

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Hydrazones
Metals
Magnetic moments
Chemical analysis
oligomycin sensitivity-conferring protein
Hot Temperature
2-hydrazinobenzothiazole
2-hydroxy-1-naphthaldehyde

All Science Journal Classification (ASJC) codes

  • Inorganic Chemistry
  • Metals and Alloys
  • Materials Chemistry

Cite this

Girish, S. R., Revankar, V. K., & Mahale, V. B. (1996). Oxomolybdenum(V) complexes of 2-benzothiazolyl hydrazones. Transition Metal Chemistry, 21(5), 401-405.
Girish, Sharada R. ; Revankar, Vidyanand K. ; Mahale, Vinayak B. / Oxomolybdenum(V) complexes of 2-benzothiazolyl hydrazones. In: Transition Metal Chemistry. 1996 ; Vol. 21, No. 5. pp. 401-405.
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Girish, SR, Revankar, VK & Mahale, VB 1996, 'Oxomolybdenum(V) complexes of 2-benzothiazolyl hydrazones', Transition Metal Chemistry, vol. 21, no. 5, pp. 401-405.

Oxomolybdenum(V) complexes of 2-benzothiazolyl hydrazones. / Girish, Sharada R.; Revankar, Vidyanand K.; Mahale, Vinayak B.

In: Transition Metal Chemistry, Vol. 21, No. 5, 10.1996, p. 401-405.

Research output: Contribution to journalArticle

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AU - Girish, Sharada R.

AU - Revankar, Vidyanand K.

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AB - Oxomolybdenum(V) complexes of general formulae [Mo2O3L2Cl2]H2O and [Mo2O3L2(OH)2(H2O) 2] (LH = hydrazones derived from 2-hydrazinobenzothiazole with salicyladehyde, 5-methyl-, 5-chloro-, 5-bromo-, 3-methoxysalicyldehyde and 2-hydroxy-1-naphthaldehyde) have been prepared and characterized by elemental analysis, conductivities, magnetic moments, thermal studies, and i.r., u.v.-vis. and e.p.r. spectra. The data suggest that the complexes are non-electrolytes, paramagnetic and have distorted octahedral structures with possible metal-metal interactions via oxo bridging.

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Girish SR, Revankar VK, Mahale VB. Oxomolybdenum(V) complexes of 2-benzothiazolyl hydrazones. Transition Metal Chemistry. 1996 Oct;21(5):401-405.