Preparation and characterization of phosphoric acid-doped hydroxyethyl cellulose electrolyte for use in supercapacitor

Y. N. Sudhakar, M. Selvakumar, D. Krishna Bhat

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

A new borax cross-linked biodegradable solid polymer electrolyte based on hydroxyethyl cellulose and phosphoric acid (H3PO4) was prepared. Characterizations of doped and undoped SPE were done using Fourier transform infrared spectroscopic and electrochemical studies. The ionic conductivity of the films increased with increase in acid concentration and the ionic conductivity obtained at 303 K was 4.1 × 10-3 S cm-1. Furthermore, effects of acid concentration on ionic conductivity and activation energy were discussed. Dielectric studies showed long tail-like feature indicating capacitive nature. A supercapacitor was fabricated and its electrochemical characteristics were studied. The supercapacitor showed a fairly good specific capacitance of 83 F g-1 at 2 mV s-1 and galvanostatic charge-discharge studies showed the mirror-like pattern with 98 % columbic efficiency. Cyclic stability was measured up to 2000 cycles.

Original languageEnglish
Article number10
JournalMaterials for Renewable and Sustainable Energy
Volume4
Issue number3
DOIs
Publication statusPublished - 01-09-2015

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Phosphoric acid
Ionic conductivity
Cellulose
Electrolytes
Sodium borate
Acids
Fourier transforms
Polymers
Mirrors
Capacitance
Activation energy
Infrared radiation
Supercapacitor
phosphoric acid

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Renewable Energy, Sustainability and the Environment
  • Fuel Technology
  • Materials Chemistry

Cite this

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abstract = "A new borax cross-linked biodegradable solid polymer electrolyte based on hydroxyethyl cellulose and phosphoric acid (H3PO4) was prepared. Characterizations of doped and undoped SPE were done using Fourier transform infrared spectroscopic and electrochemical studies. The ionic conductivity of the films increased with increase in acid concentration and the ionic conductivity obtained at 303 K was 4.1 × 10-3 S cm-1. Furthermore, effects of acid concentration on ionic conductivity and activation energy were discussed. Dielectric studies showed long tail-like feature indicating capacitive nature. A supercapacitor was fabricated and its electrochemical characteristics were studied. The supercapacitor showed a fairly good specific capacitance of 83 F g-1 at 2 mV s-1 and galvanostatic charge-discharge studies showed the mirror-like pattern with 98 {\%} columbic efficiency. Cyclic stability was measured up to 2000 cycles.",
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Preparation and characterization of phosphoric acid-doped hydroxyethyl cellulose electrolyte for use in supercapacitor. / Sudhakar, Y. N.; Selvakumar, M.; Bhat, D. Krishna.

In: Materials for Renewable and Sustainable Energy, Vol. 4, No. 3, 10, 01.09.2015.

Research output: Contribution to journalArticle

TY - JOUR

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AU - Selvakumar, M.

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AB - A new borax cross-linked biodegradable solid polymer electrolyte based on hydroxyethyl cellulose and phosphoric acid (H3PO4) was prepared. Characterizations of doped and undoped SPE were done using Fourier transform infrared spectroscopic and electrochemical studies. The ionic conductivity of the films increased with increase in acid concentration and the ionic conductivity obtained at 303 K was 4.1 × 10-3 S cm-1. Furthermore, effects of acid concentration on ionic conductivity and activation energy were discussed. Dielectric studies showed long tail-like feature indicating capacitive nature. A supercapacitor was fabricated and its electrochemical characteristics were studied. The supercapacitor showed a fairly good specific capacitance of 83 F g-1 at 2 mV s-1 and galvanostatic charge-discharge studies showed the mirror-like pattern with 98 % columbic efficiency. Cyclic stability was measured up to 2000 cycles.

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