Reactivity of tricarbonyl(η5-cyclopentadienyl)(dimethyldithiocarbamato)tungsten towards coordinatively unsaturated species

Pradeep Mathur, B. H.S. Thimmappa

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

Visible light irradiation of solutions containing [(η5-C5H5)(CO)3 WSC(S)NMe2] (1) and Fe2(CO)9 or Mn2(CO)10 leads to a transmetallation type of reaction and formation of Fe(S2CNMe2)2 and Mn(CO)4(S2CNMe2) respectively. However, the reaction or 1 with M(PPh3)4, M = Pt, or Pd, leads to conversion to the dicarbonyl chelate complex [(η5C2H5(CO)2 W(S2CNMe2)].

Original languageEnglish
Pages (from-to)119-122
Number of pages4
JournalInorganica Chimica Acta
Volume148
Issue number1
DOIs
Publication statusPublished - 01-08-1988

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Tungsten
Carbon Monoxide
tungsten
reactivity
Irradiation
chelates
irradiation

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

Cite this

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title = "Reactivity of tricarbonyl(η5-cyclopentadienyl)(dimethyldithiocarbamato)tungsten towards coordinatively unsaturated species",
abstract = "Visible light irradiation of solutions containing [(η5-C5H5)(CO)3 WSC(S)NMe2] (1) and Fe2(CO)9 or Mn2(CO)10 leads to a transmetallation type of reaction and formation of Fe(S2CNMe2)2 and Mn(CO)4(S2CNMe2) respectively. However, the reaction or 1 with M(PPh3)4, M = Pt, or Pd, leads to conversion to the dicarbonyl chelate complex [(η5C2H5(CO)2 W(S2CNMe2)].",
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Reactivity of tricarbonyl(η5-cyclopentadienyl)(dimethyldithiocarbamato)tungsten towards coordinatively unsaturated species. / Mathur, Pradeep; Thimmappa, B. H.S.

In: Inorganica Chimica Acta, Vol. 148, No. 1, 01.08.1988, p. 119-122.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Reactivity of tricarbonyl(η5-cyclopentadienyl)(dimethyldithiocarbamato)tungsten towards coordinatively unsaturated species

AU - Mathur, Pradeep

AU - Thimmappa, B. H.S.

PY - 1988/8/1

Y1 - 1988/8/1

N2 - Visible light irradiation of solutions containing [(η5-C5H5)(CO)3 WSC(S)NMe2] (1) and Fe2(CO)9 or Mn2(CO)10 leads to a transmetallation type of reaction and formation of Fe(S2CNMe2)2 and Mn(CO)4(S2CNMe2) respectively. However, the reaction or 1 with M(PPh3)4, M = Pt, or Pd, leads to conversion to the dicarbonyl chelate complex [(η5C2H5(CO)2 W(S2CNMe2)].

AB - Visible light irradiation of solutions containing [(η5-C5H5)(CO)3 WSC(S)NMe2] (1) and Fe2(CO)9 or Mn2(CO)10 leads to a transmetallation type of reaction and formation of Fe(S2CNMe2)2 and Mn(CO)4(S2CNMe2) respectively. However, the reaction or 1 with M(PPh3)4, M = Pt, or Pd, leads to conversion to the dicarbonyl chelate complex [(η5C2H5(CO)2 W(S2CNMe2)].

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JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

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