Reactivity of tricarbonyl(η5-cyclopentadienyl)(dimethyldithiocarbamato)tungsten towards coordinatively unsaturated species

Pradeep Mathur, B. H.S. Thimmappa

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

Visible light irradiation of solutions containing [(η5-C5H5)(CO)3 WSC(S)NMe2] (1) and Fe2(CO)9 or Mn2(CO)10 leads to a transmetallation type of reaction and formation of Fe(S2CNMe2)2 and Mn(CO)4(S2CNMe2) respectively. However, the reaction or 1 with M(PPh3)4, M = Pt, or Pd, leads to conversion to the dicarbonyl chelate complex [(η5C2H5(CO)2 W(S2CNMe2)].

Original languageEnglish
Pages (from-to)119-122
Number of pages4
JournalInorganica Chimica Acta
Volume148
Issue number1
DOIs
Publication statusPublished - 01-08-1988

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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