Redetermination of methyl 3,4-O-isopropyl-idene-Β-D-fucopyran-oside monohydrate

Hoong Kun Fun, Samuel Robinson Jebas, Sankappa Rai, Prakash Shetty, Arun M. Isloor

Research output: Contribution to journalArticle

Abstract

In the title compound, C10H18O5· H2O, the fucopyran-oside ring adopts a chair conformation. The crystal packing is stabilized by inter-molecular O - H⋯O and C - H⋯O hydrogen bonds together with intra-molecular O⋯O [2.2936 (8) Å] and inter-molecular O⋯O [2.7140 (8)-2.829 (3) Å] short contacts. The mol-ecules are linked together to form an infinite chain along the a axis. This structure has been solved previously but with no R-values [Spiers (1931). Z. Kristallogr. Kristallgeom. Kristallphys. Kristallchem. 78, 101].

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume65
Issue number5
DOIs
Publication statusPublished - 15-06-2009

Fingerprint

seats
Conformations
Hydrogen bonds
hydrogen bonds
Crystals
rings
crystals

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

Fun, Hoong Kun ; Jebas, Samuel Robinson ; Rai, Sankappa ; Shetty, Prakash ; Isloor, Arun M. / Redetermination of methyl 3,4-O-isopropyl-idene-Β-D-fucopyran-oside monohydrate. In: Acta Crystallographica Section E: Structure Reports Online. 2009 ; Vol. 65, No. 5.
@article{28e0cf5d55834cd58982474aff856ad6,
title = "Redetermination of methyl 3,4-O-isopropyl-idene-Β-D-fucopyran-oside monohydrate",
abstract = "In the title compound, C10H18O5· H2O, the fucopyran-oside ring adopts a chair conformation. The crystal packing is stabilized by inter-molecular O - H⋯O and C - H⋯O hydrogen bonds together with intra-molecular O⋯O [2.2936 (8) {\AA}] and inter-molecular O⋯O [2.7140 (8)-2.829 (3) {\AA}] short contacts. The mol-ecules are linked together to form an infinite chain along the a axis. This structure has been solved previously but with no R-values [Spiers (1931). Z. Kristallogr. Kristallgeom. Kristallphys. Kristallchem. 78, 101].",
author = "Fun, {Hoong Kun} and Jebas, {Samuel Robinson} and Sankappa Rai and Prakash Shetty and Isloor, {Arun M.}",
year = "2009",
month = "6",
day = "15",
doi = "10.1107/S1600536809012689",
language = "English",
volume = "65",
journal = "Acta Crystallographica Section E: Structure Reports Online",
issn = "1600-5368",
publisher = "International Union of Crystallography",
number = "5",

}

Redetermination of methyl 3,4-O-isopropyl-idene-Β-D-fucopyran-oside monohydrate. / Fun, Hoong Kun; Jebas, Samuel Robinson; Rai, Sankappa; Shetty, Prakash; Isloor, Arun M.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 65, No. 5, 15.06.2009.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Redetermination of methyl 3,4-O-isopropyl-idene-Β-D-fucopyran-oside monohydrate

AU - Fun, Hoong Kun

AU - Jebas, Samuel Robinson

AU - Rai, Sankappa

AU - Shetty, Prakash

AU - Isloor, Arun M.

PY - 2009/6/15

Y1 - 2009/6/15

N2 - In the title compound, C10H18O5· H2O, the fucopyran-oside ring adopts a chair conformation. The crystal packing is stabilized by inter-molecular O - H⋯O and C - H⋯O hydrogen bonds together with intra-molecular O⋯O [2.2936 (8) Å] and inter-molecular O⋯O [2.7140 (8)-2.829 (3) Å] short contacts. The mol-ecules are linked together to form an infinite chain along the a axis. This structure has been solved previously but with no R-values [Spiers (1931). Z. Kristallogr. Kristallgeom. Kristallphys. Kristallchem. 78, 101].

AB - In the title compound, C10H18O5· H2O, the fucopyran-oside ring adopts a chair conformation. The crystal packing is stabilized by inter-molecular O - H⋯O and C - H⋯O hydrogen bonds together with intra-molecular O⋯O [2.2936 (8) Å] and inter-molecular O⋯O [2.7140 (8)-2.829 (3) Å] short contacts. The mol-ecules are linked together to form an infinite chain along the a axis. This structure has been solved previously but with no R-values [Spiers (1931). Z. Kristallogr. Kristallgeom. Kristallphys. Kristallchem. 78, 101].

UR - http://www.scopus.com/inward/record.url?scp=66749128537&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=66749128537&partnerID=8YFLogxK

U2 - 10.1107/S1600536809012689

DO - 10.1107/S1600536809012689

M3 - Article

AN - SCOPUS:66749128537

VL - 65

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

SN - 1600-5368

IS - 5

ER -