Studies on biosorption of methylene blue from aqueous solutions by powdered palm tree flower (Borassus flabellifer)

M. Srinivas Kini, M. B. Saidutta, V. Ramachandra Murty

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6 Citations (Scopus)

Abstract

Biosorption experiments were carried out for the removal of methylene blue (MB) using palm tree male flower (PTMF) as the biosorbent at various pH, temperature, biosorbent, and adsorbate concentration. The optimum pH was found to be 6.0. The kinetic data were fitted in pseudofirst-order and second-order models. The equilibrium data were well-fitted in Langmuir isotherm and the maximum equilibrium capacities of the biosorbent were found to be 143.6, 153,9, 157.3 mg/g at 303, 313, and 323 K, respectively. Thermodynamic data for the adsorption system indicated spontaneous and endothermic process. The enthalpy and entropy values for adsorption were obtained as 15.06 KJ/mol and 0.129 KJ/mol K, respectively, in the temperature range of 303-323 K. A mathematical model for MB transported by molecular diffusion from the bulk of the solution to the surface of PTMF was derived and the values of liquid phase diffusivity and external mass transfer coefficient were estimated.

Original languageEnglish
Article number306519
JournalInternational Journal of Chemical Engineering
DOIs
Publication statusPublished - 2014

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Biosorption
Methylene Blue
Adsorption
Adsorbates
Isotherms
Enthalpy
Entropy
Mass transfer
Thermodynamics
Mathematical models
Temperature
Kinetics
Liquids
Experiments

All Science Journal Classification (ASJC) codes

  • Chemical Engineering(all)

Cite this

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title = "Studies on biosorption of methylene blue from aqueous solutions by powdered palm tree flower (Borassus flabellifer)",
abstract = "Biosorption experiments were carried out for the removal of methylene blue (MB) using palm tree male flower (PTMF) as the biosorbent at various pH, temperature, biosorbent, and adsorbate concentration. The optimum pH was found to be 6.0. The kinetic data were fitted in pseudofirst-order and second-order models. The equilibrium data were well-fitted in Langmuir isotherm and the maximum equilibrium capacities of the biosorbent were found to be 143.6, 153,9, 157.3 mg/g at 303, 313, and 323 K, respectively. Thermodynamic data for the adsorption system indicated spontaneous and endothermic process. The enthalpy and entropy values for adsorption were obtained as 15.06 KJ/mol and 0.129 KJ/mol K, respectively, in the temperature range of 303-323 K. A mathematical model for MB transported by molecular diffusion from the bulk of the solution to the surface of PTMF was derived and the values of liquid phase diffusivity and external mass transfer coefficient were estimated.",
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AU - Kini, M. Srinivas

AU - Saidutta, M. B.

AU - Murty, V. Ramachandra

PY - 2014

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N2 - Biosorption experiments were carried out for the removal of methylene blue (MB) using palm tree male flower (PTMF) as the biosorbent at various pH, temperature, biosorbent, and adsorbate concentration. The optimum pH was found to be 6.0. The kinetic data were fitted in pseudofirst-order and second-order models. The equilibrium data were well-fitted in Langmuir isotherm and the maximum equilibrium capacities of the biosorbent were found to be 143.6, 153,9, 157.3 mg/g at 303, 313, and 323 K, respectively. Thermodynamic data for the adsorption system indicated spontaneous and endothermic process. The enthalpy and entropy values for adsorption were obtained as 15.06 KJ/mol and 0.129 KJ/mol K, respectively, in the temperature range of 303-323 K. A mathematical model for MB transported by molecular diffusion from the bulk of the solution to the surface of PTMF was derived and the values of liquid phase diffusivity and external mass transfer coefficient were estimated.

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