Synthesis and characterization of novel chiral imidazolium and pyridinium ionic liquids derived from tartaric acid and 2-oxazolidinone

Sagar P. Nehate, Himanshu M. Godbole, Girij P. Singh, Jessy E. Mathew, Gautham G. Shenoy

Research output: Contribution to journalArticle

Abstract

Novel chiral imidazolium and pyridinium ionic liquids based on tartaric acid and 2-oxazolidinone were designed. Symmetrical dicationic ionic liquids based on tartaric acid have been synthesized and characterized. These chiral ionic liquids were designed by employing very short and simple methods. Incorporation of alkyl halide over tartaric acid and 2-oxazolidinone is an important step. N-methyl imidazole and pyridine were used for preparation of quaternary salts. These ionic liquids have been evaluated for the asymmetric sulfide oxidation. Chiral ionic liquids based on tartaric acid showed superior chiral inducing property as compare to 2-oxazolidinone based chiral ionic liquids.

Original languageEnglish
Pages (from-to)1173-1180
Number of pages8
JournalSynthetic Communications
Volume49
Issue number9
DOIs
Publication statusPublished - 03-05-2019

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Oxazolidinones
Ionic Liquids
Sulfides
tartaric acid
Salts
Oxidation

All Science Journal Classification (ASJC) codes

  • Organic Chemistry

Cite this

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title = "Synthesis and characterization of novel chiral imidazolium and pyridinium ionic liquids derived from tartaric acid and 2-oxazolidinone",
abstract = "Novel chiral imidazolium and pyridinium ionic liquids based on tartaric acid and 2-oxazolidinone were designed. Symmetrical dicationic ionic liquids based on tartaric acid have been synthesized and characterized. These chiral ionic liquids were designed by employing very short and simple methods. Incorporation of alkyl halide over tartaric acid and 2-oxazolidinone is an important step. N-methyl imidazole and pyridine were used for preparation of quaternary salts. These ionic liquids have been evaluated for the asymmetric sulfide oxidation. Chiral ionic liquids based on tartaric acid showed superior chiral inducing property as compare to 2-oxazolidinone based chiral ionic liquids.",
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Synthesis and characterization of novel chiral imidazolium and pyridinium ionic liquids derived from tartaric acid and 2-oxazolidinone. / Nehate, Sagar P.; Godbole, Himanshu M.; Singh, Girij P.; Mathew, Jessy E.; Shenoy, Gautham G.

In: Synthetic Communications, Vol. 49, No. 9, 03.05.2019, p. 1173-1180.

Research output: Contribution to journalArticle

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AU - Nehate, Sagar P.

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AU - Mathew, Jessy E.

AU - Shenoy, Gautham G.

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AB - Novel chiral imidazolium and pyridinium ionic liquids based on tartaric acid and 2-oxazolidinone were designed. Symmetrical dicationic ionic liquids based on tartaric acid have been synthesized and characterized. These chiral ionic liquids were designed by employing very short and simple methods. Incorporation of alkyl halide over tartaric acid and 2-oxazolidinone is an important step. N-methyl imidazole and pyridine were used for preparation of quaternary salts. These ionic liquids have been evaluated for the asymmetric sulfide oxidation. Chiral ionic liquids based on tartaric acid showed superior chiral inducing property as compare to 2-oxazolidinone based chiral ionic liquids.

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