Synthesis and Characterization of Reduced Graphene Oxide for Supercapacitor Application with a Biodegradable Electrolyte

S. Adarsh Rag, M. Selvakumar, Somashekara Bhat, Santhosh Chidangil, Shounak De

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Abstract

The possibility of synthesizing a proton-conducting biopolymer electrolyte of polyvinyl alcohol (PVA) doped with 1-ethyl-3-methylimidazolium ethyl sulphate ([EMIM][EtSO4]) ionic liquid and ammonium acetate (CH3COONH4) by solvent casting has been investigated. The ionic conductivity of electrolyte membrane increased with addition of IL and fairly good ionic conductivity of 6.56 × 10−4 S cm−1 has been attained. The conductivity studies of the biopolymer electrolyte membrane have been carried out in coplanar configuration. Graphene oxide (GO) and reduced graphene oxide (rGO) have been synthesized by a chemical method. The prepared rGO has been characterized using ultraviolet–visible (UV–Vis) absorption spectroscopy, x-ray diffraction, Raman and x-ray photoelectron spectroscopy analysis. The surface area of rGO has been increased from 2.69 m2 g−1 to 203.78 m2 g−1. In this work, a supercapacitor with a symmetric electrode has been fabricated using PVA-doped ionic liquid as a biopolymer electrolyte and rGO as electrode materials. Its electrochemical performance has been verified, and the device exhibited a good specific capacitance of 138 F g−1. This combination was found to be very useful to improve the capacitance of supercapacitor.

Original languageEnglish
JournalJournal of Electronic Materials
DOIs
Publication statusPublished - 01-02-2020

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All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics
  • Electrical and Electronic Engineering
  • Materials Chemistry

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