Synthesis and Characterization of the New Clusters Ru4(CO)114-Te)2, Ru3(CO)6(PPh3)33-Te)2, Ru4(CO)10(PPh3)(μ4-Te)2, and Ru4(CO)9(μ-Ph2PCH2PPh2)(μ4Te)2

Pradeep Mathur, B. H.S. Thimmappa, Arnold L. Rheingold

Research output: Contribution to journalArticle

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Abstract

The compound Ru4(CO)114-Te)2(1) has been prepared by refluxing a benzene solution containing Fe3(CO)93-Te)2and Ru3(CO)12. The compounds Ru3(CO)6(PPh3)33-Te)2(2) and Ru4(CO)10(PPh3)(μ4-Te)2(3) were obtained from the room-temperature reaction of 1 with PPh3. Similarly, Ru4(CO)9(μ-Ph2PCH2PPh2)(μ4-Te)2(4) was obtained from the reaction of 1 with Ph2PCH2PPh2at room temperature. The structure of 1–4 were established by single-crystal X-ray diffraction analysis. Crystal data: 1, orthorhombic, Pccn, a = 6.924 (2) Å, b = 16.289 (6) Å, c = 18.054 (6) Å, V = 2036 (1) Å3, Z = 4, R(F) = 4.16%; 2, monoclinic, P21/n, a = 10.539 (4) Å, b = 27.39 (1) Å, c = 20.415 (7) Å, β = 94.96 (3)°, V= 5870 (4) Å3, Z = 4, R(F) = 4.96%; 3, orthorhombic, Pbca, a = 19.070 (5) Å, b = 18.157 (4) Å, c = 19.272 (5) Å, V= 6673 (3) Å3, Z = 8, R(F) = 3.65%; 4, triclinic, P1, a = 13.255 (3) Å, b = 17.610 (5) Å, c = 19.189 (5) Å, α = 65.39 (2)°, β = 78.25 (2)°, γ = 84.13 (2)°, V = 3986 (2) Å3, Z = 4, R(F) = 2.97%.

Original languageEnglish
Pages (from-to)4658-4665
Number of pages8
JournalInorganic Chemistry
Volume29
Issue number23
DOIs
Publication statusPublished - 01-01-1990

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room temperature
synthesis
Benzene
X ray diffraction analysis
benzene
Single crystals
Temperature
Crystals
single crystals
diffraction
crystals
x rays

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

Cite this

@article{0dc4ef36ee7943c2ace7ecd4684954d1,
title = "Synthesis and Characterization of the New Clusters Ru4(CO)11(μ4-Te)2, Ru3(CO)6(PPh3)3(μ3-Te)2, Ru4(CO)10(PPh3)(μ4-Te)2, and Ru4(CO)9(μ-Ph2PCH2PPh2)(μ4Te)2",
abstract = "The compound Ru4(CO)11(μ4-Te)2(1) has been prepared by refluxing a benzene solution containing Fe3(CO)9(μ3-Te)2and Ru3(CO)12. The compounds Ru3(CO)6(PPh3)3(μ3-Te)2(2) and Ru4(CO)10(PPh3)(μ4-Te)2(3) were obtained from the room-temperature reaction of 1 with PPh3. Similarly, Ru4(CO)9(μ-Ph2PCH2PPh2)(μ4-Te)2(4) was obtained from the reaction of 1 with Ph2PCH2PPh2at room temperature. The structure of 1–4 were established by single-crystal X-ray diffraction analysis. Crystal data: 1, orthorhombic, Pccn, a = 6.924 (2) {\AA}, b = 16.289 (6) {\AA}, c = 18.054 (6) {\AA}, V = 2036 (1) {\AA}3, Z = 4, R(F) = 4.16{\%}; 2, monoclinic, P21/n, a = 10.539 (4) {\AA}, b = 27.39 (1) {\AA}, c = 20.415 (7) {\AA}, β = 94.96 (3)°, V= 5870 (4) {\AA}3, Z = 4, R(F) = 4.96{\%}; 3, orthorhombic, Pbca, a = 19.070 (5) {\AA}, b = 18.157 (4) {\AA}, c = 19.272 (5) {\AA}, V= 6673 (3) {\AA}3, Z = 8, R(F) = 3.65{\%}; 4, triclinic, P1, a = 13.255 (3) {\AA}, b = 17.610 (5) {\AA}, c = 19.189 (5) {\AA}, α = 65.39 (2)°, β = 78.25 (2)°, γ = 84.13 (2)°, V = 3986 (2) {\AA}3, Z = 4, R(F) = 2.97{\%}.",
author = "Pradeep Mathur and Thimmappa, {B. H.S.} and Rheingold, {Arnold L.}",
year = "1990",
month = "1",
day = "1",
doi = "10.1021/ic00348a015",
language = "English",
volume = "29",
pages = "4658--4665",
journal = "Inorganic Chemistry",
issn = "0020-1669",
publisher = "American Chemical Society",
number = "23",

}

Synthesis and Characterization of the New Clusters Ru4(CO)114-Te)2, Ru3(CO)6(PPh3)33-Te)2, Ru4(CO)10(PPh3)(μ4-Te)2, and Ru4(CO)9(μ-Ph2PCH2PPh2)(μ4Te)2. / Mathur, Pradeep; Thimmappa, B. H.S.; Rheingold, Arnold L.

In: Inorganic Chemistry, Vol. 29, No. 23, 01.01.1990, p. 4658-4665.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Synthesis and Characterization of the New Clusters Ru4(CO)11(μ4-Te)2, Ru3(CO)6(PPh3)3(μ3-Te)2, Ru4(CO)10(PPh3)(μ4-Te)2, and Ru4(CO)9(μ-Ph2PCH2PPh2)(μ4Te)2

AU - Mathur, Pradeep

AU - Thimmappa, B. H.S.

AU - Rheingold, Arnold L.

PY - 1990/1/1

Y1 - 1990/1/1

N2 - The compound Ru4(CO)11(μ4-Te)2(1) has been prepared by refluxing a benzene solution containing Fe3(CO)9(μ3-Te)2and Ru3(CO)12. The compounds Ru3(CO)6(PPh3)3(μ3-Te)2(2) and Ru4(CO)10(PPh3)(μ4-Te)2(3) were obtained from the room-temperature reaction of 1 with PPh3. Similarly, Ru4(CO)9(μ-Ph2PCH2PPh2)(μ4-Te)2(4) was obtained from the reaction of 1 with Ph2PCH2PPh2at room temperature. The structure of 1–4 were established by single-crystal X-ray diffraction analysis. Crystal data: 1, orthorhombic, Pccn, a = 6.924 (2) Å, b = 16.289 (6) Å, c = 18.054 (6) Å, V = 2036 (1) Å3, Z = 4, R(F) = 4.16%; 2, monoclinic, P21/n, a = 10.539 (4) Å, b = 27.39 (1) Å, c = 20.415 (7) Å, β = 94.96 (3)°, V= 5870 (4) Å3, Z = 4, R(F) = 4.96%; 3, orthorhombic, Pbca, a = 19.070 (5) Å, b = 18.157 (4) Å, c = 19.272 (5) Å, V= 6673 (3) Å3, Z = 8, R(F) = 3.65%; 4, triclinic, P1, a = 13.255 (3) Å, b = 17.610 (5) Å, c = 19.189 (5) Å, α = 65.39 (2)°, β = 78.25 (2)°, γ = 84.13 (2)°, V = 3986 (2) Å3, Z = 4, R(F) = 2.97%.

AB - The compound Ru4(CO)11(μ4-Te)2(1) has been prepared by refluxing a benzene solution containing Fe3(CO)9(μ3-Te)2and Ru3(CO)12. The compounds Ru3(CO)6(PPh3)3(μ3-Te)2(2) and Ru4(CO)10(PPh3)(μ4-Te)2(3) were obtained from the room-temperature reaction of 1 with PPh3. Similarly, Ru4(CO)9(μ-Ph2PCH2PPh2)(μ4-Te)2(4) was obtained from the reaction of 1 with Ph2PCH2PPh2at room temperature. The structure of 1–4 were established by single-crystal X-ray diffraction analysis. Crystal data: 1, orthorhombic, Pccn, a = 6.924 (2) Å, b = 16.289 (6) Å, c = 18.054 (6) Å, V = 2036 (1) Å3, Z = 4, R(F) = 4.16%; 2, monoclinic, P21/n, a = 10.539 (4) Å, b = 27.39 (1) Å, c = 20.415 (7) Å, β = 94.96 (3)°, V= 5870 (4) Å3, Z = 4, R(F) = 4.96%; 3, orthorhombic, Pbca, a = 19.070 (5) Å, b = 18.157 (4) Å, c = 19.272 (5) Å, V= 6673 (3) Å3, Z = 8, R(F) = 3.65%; 4, triclinic, P1, a = 13.255 (3) Å, b = 17.610 (5) Å, c = 19.189 (5) Å, α = 65.39 (2)°, β = 78.25 (2)°, γ = 84.13 (2)°, V = 3986 (2) Å3, Z = 4, R(F) = 2.97%.

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