Synthesis, structural investigations and biological studies on symmetrically substituted 4,4',4'',4'''- tetra-methoxyphenylimino phthalocyanine complexes

M. H.Moinuddin Khan, Fasiulla, M. N.K. Harish, J. Keshavayya, K. R.Venugopala Reddy

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Abstract

The synthesis and characterization of novel metal(II) 4,4',4'',4'''-tetra- methoxyphenylimino substituted phthalocyanines (MImPc) of copper(II), cobalt(II), nickel(II) and zinc(II) by condensing the 4,4',4'',4'''-tetra amino phthalocyanines with anisaldehyde are described. The dark bluish green colored tetraimino substituted phthalocyanine derivatives are characterized by various physico-chemical techniques, elemental analysis, magnetic susceptibility, electronic, and IR spectra, powder X-ray diffraction and thermo gravimetric analysis (TGA) to check the structural integrity and purity. The variations of magnetic moment as a function of field strength indicated the presence of intermolecular co-operative interactions. The complexes are also evaluated for their antifungal and antibacterial activities.

Original languageEnglish
Pages (from-to)1255-1267
Number of pages13
JournalJournal of Coordination Chemistry
Volume60
Issue number12
DOIs
Publication statusPublished - 01-06-2007

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All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Materials Chemistry

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