Synthesis, structural investigations studies on symmetrically substituted metal (II) 1, 3, 8, 10, 15, 17, 22, 24-octa-1-(3-nitrophenyl) methaniminephthalocyanine

Fasiulla, K. R. Venugopala Reddy, J. Keshavayya, B. Chandrashekar Kumar, Anitha, Vittala Rao

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Abstract

Present paper discuss the synthesis and characterization of metal (II) 1, 3, 8, 10, 15, 17, 22, 24-octa-1-(3-nitro phenyl)methaniminephthalocyanines(M-NPhImPcO) (M = Cu, Co, Ni, Zn) by an efficient, simple, and novel method. Octaamino metal (II) phthalocyanines were synthesized by the reduction of the corresponding nitro phthalocyanines. The dark green octa-1-(3-nitrophenyl) methaniminephthalocyanine derivatives were characterized by elemental analysis, magnetic susceptibility, electronic, IR and powder X-ray diffraction studies to check the purity, structural integrity and crystalline properties of the complexes. Magnetic susceptibility studies on Co (II) and Cu (II) octa-1-(3-nitrophenyl) methaniminephthalocyanine complexes exhibit a variation of the magnetic moments as a function of field strength indicating the presence of inter molecular co-operative effect.

Original languageEnglish
Pages (from-to)205-212
Number of pages8
JournalJournal of Chemical and Pharmaceutical Research
Volume5
Issue number1
Publication statusPublished - 05-03-2013

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All Science Journal Classification (ASJC) codes

  • Pharmaceutical Science

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