Synthesis, structural investigations studies on symmetrically substituted metal (II) 1, 3, 8, 10, 15, 17, 22, 24-octa-1-(3-nitrophenyl) methaniminephthalocyanine

Fasiulla, K. R. Venugopala Reddy, J. Keshavayya, B. Chandrashekar Kumar, Anitha, Vittala Rao

Research output: Contribution to journalArticle

Abstract

Present paper discuss the synthesis and characterization of metal (II) 1, 3, 8, 10, 15, 17, 22, 24-octa-1-(3-nitro phenyl)methaniminephthalocyanines(M-NPhImPcO) (M = Cu, Co, Ni, Zn) by an efficient, simple, and novel method. Octaamino metal (II) phthalocyanines were synthesized by the reduction of the corresponding nitro phthalocyanines. The dark green octa-1-(3-nitrophenyl) methaniminephthalocyanine derivatives were characterized by elemental analysis, magnetic susceptibility, electronic, IR and powder X-ray diffraction studies to check the purity, structural integrity and crystalline properties of the complexes. Magnetic susceptibility studies on Co (II) and Cu (II) octa-1-(3-nitrophenyl) methaniminephthalocyanine complexes exhibit a variation of the magnetic moments as a function of field strength indicating the presence of inter molecular co-operative effect.

Original languageEnglish
Pages (from-to)205-212
Number of pages8
JournalJournal of Chemical and Pharmaceutical Research
Volume5
Issue number1
Publication statusPublished - 05-03-2013
Externally publishedYes

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Metals
X-Ray Diffraction
Powders
phthalocyanine

All Science Journal Classification (ASJC) codes

  • Pharmaceutical Science

Cite this

Fasiulla ; Venugopala Reddy, K. R. ; Keshavayya, J. ; Chandrashekar Kumar, B. ; Anitha ; Rao, Vittala. / Synthesis, structural investigations studies on symmetrically substituted metal (II) 1, 3, 8, 10, 15, 17, 22, 24-octa-1-(3-nitrophenyl) methaniminephthalocyanine. In: Journal of Chemical and Pharmaceutical Research. 2013 ; Vol. 5, No. 1. pp. 205-212.
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abstract = "Present paper discuss the synthesis and characterization of metal (II) 1, 3, 8, 10, 15, 17, 22, 24-octa-1-(3-nitro phenyl)methaniminephthalocyanines(M-NPhImPcO) (M = Cu, Co, Ni, Zn) by an efficient, simple, and novel method. Octaamino metal (II) phthalocyanines were synthesized by the reduction of the corresponding nitro phthalocyanines. The dark green octa-1-(3-nitrophenyl) methaniminephthalocyanine derivatives were characterized by elemental analysis, magnetic susceptibility, electronic, IR and powder X-ray diffraction studies to check the purity, structural integrity and crystalline properties of the complexes. Magnetic susceptibility studies on Co (II) and Cu (II) octa-1-(3-nitrophenyl) methaniminephthalocyanine complexes exhibit a variation of the magnetic moments as a function of field strength indicating the presence of inter molecular co-operative effect.",
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Synthesis, structural investigations studies on symmetrically substituted metal (II) 1, 3, 8, 10, 15, 17, 22, 24-octa-1-(3-nitrophenyl) methaniminephthalocyanine. / Fasiulla; Venugopala Reddy, K. R.; Keshavayya, J.; Chandrashekar Kumar, B.; Anitha; Rao, Vittala.

In: Journal of Chemical and Pharmaceutical Research, Vol. 5, No. 1, 05.03.2013, p. 205-212.

Research output: Contribution to journalArticle

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