Tailoring the nonlinear optical susceptibility χ(3), photoluminescence and optical band gap of nanostructured SnO2 thin films by Zn doping for photonic device applications

M. S. Bannur, Albin Antony, K. I. Maddani, P. Poornesh, Ashok Rao, K. S. Choudhari

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

We report the influence of Zinc (Zn) doping on the structural, optical, and nonlinear optical properties of tin oxide (SnO2) thin films prepared by chemical spray pyrolysis technique. The photoluminescence studies shows the formation of oxygen vacancy defect states upon Zn incorporation. Nonlinear behavior observed in NBE emission were attributed to variations in the crystallinity of the samples upon Zn incorporation. X-Ray diffraction patterns reveals that all the films are polycrystalline in nature having tetragonal rutile structure. The band gap energy values decreased from 3.71 eV to 3.30 eV with increase in the Zn concentration due to formation of defect states and atomic structural disordering. The surface morphology and average surface roughness of the samples were investigated using Atomic force microscopy which endorses the shift from the crystalline state to the amorphous state. The sign and magnitude of nonlinear refractive index and nonlinear absorption coefficient was found out by Z-scan technique with a continuous wave laser as the excitation source. The third order optical Susceptibility χ(3) has found to be increased from 1.08 × 10−3 esu to 2.20 × 10−3 esu upon Zn incorporation. The Z-scan results reveal that the films exhibit self-defocusing nonlinearity. Enhancement in the optical nonlinearity upon doping enables the applicability of the material in various optoelectronic device applications.

Original languageEnglish
Pages (from-to)348-353
Number of pages6
JournalPhysica E: Low-Dimensional Systems and Nanostructures
Volume103
DOIs
Publication statusPublished - 01-09-2018

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Photonic devices
Optical band gaps
Zinc
Photoluminescence
zinc
Doping (additives)
photonics
magnetic permeability
photoluminescence
Thin films
thin films
nonlinearity
Defects
Continuous wave lasers
Spray pyrolysis
continuous wave lasers
defects
defocusing
Oxygen vacancies
optoelectronic devices

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Atomic and Molecular Physics, and Optics
  • Condensed Matter Physics

Cite this

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title = "Tailoring the nonlinear optical susceptibility χ(3), photoluminescence and optical band gap of nanostructured SnO2 thin films by Zn doping for photonic device applications",
abstract = "We report the influence of Zinc (Zn) doping on the structural, optical, and nonlinear optical properties of tin oxide (SnO2) thin films prepared by chemical spray pyrolysis technique. The photoluminescence studies shows the formation of oxygen vacancy defect states upon Zn incorporation. Nonlinear behavior observed in NBE emission were attributed to variations in the crystallinity of the samples upon Zn incorporation. X-Ray diffraction patterns reveals that all the films are polycrystalline in nature having tetragonal rutile structure. The band gap energy values decreased from 3.71 eV to 3.30 eV with increase in the Zn concentration due to formation of defect states and atomic structural disordering. The surface morphology and average surface roughness of the samples were investigated using Atomic force microscopy which endorses the shift from the crystalline state to the amorphous state. The sign and magnitude of nonlinear refractive index and nonlinear absorption coefficient was found out by Z-scan technique with a continuous wave laser as the excitation source. The third order optical Susceptibility χ(3) has found to be increased from 1.08 × 10−3 esu to 2.20 × 10−3 esu upon Zn incorporation. The Z-scan results reveal that the films exhibit self-defocusing nonlinearity. Enhancement in the optical nonlinearity upon doping enables the applicability of the material in various optoelectronic device applications.",
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AU - Bannur, M. S.

AU - Antony, Albin

AU - Maddani, K. I.

AU - Poornesh, P.

AU - Rao, Ashok

AU - Choudhari, K. S.

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N2 - We report the influence of Zinc (Zn) doping on the structural, optical, and nonlinear optical properties of tin oxide (SnO2) thin films prepared by chemical spray pyrolysis technique. The photoluminescence studies shows the formation of oxygen vacancy defect states upon Zn incorporation. Nonlinear behavior observed in NBE emission were attributed to variations in the crystallinity of the samples upon Zn incorporation. X-Ray diffraction patterns reveals that all the films are polycrystalline in nature having tetragonal rutile structure. The band gap energy values decreased from 3.71 eV to 3.30 eV with increase in the Zn concentration due to formation of defect states and atomic structural disordering. The surface morphology and average surface roughness of the samples were investigated using Atomic force microscopy which endorses the shift from the crystalline state to the amorphous state. The sign and magnitude of nonlinear refractive index and nonlinear absorption coefficient was found out by Z-scan technique with a continuous wave laser as the excitation source. The third order optical Susceptibility χ(3) has found to be increased from 1.08 × 10−3 esu to 2.20 × 10−3 esu upon Zn incorporation. The Z-scan results reveal that the films exhibit self-defocusing nonlinearity. Enhancement in the optical nonlinearity upon doping enables the applicability of the material in various optoelectronic device applications.

AB - We report the influence of Zinc (Zn) doping on the structural, optical, and nonlinear optical properties of tin oxide (SnO2) thin films prepared by chemical spray pyrolysis technique. The photoluminescence studies shows the formation of oxygen vacancy defect states upon Zn incorporation. Nonlinear behavior observed in NBE emission were attributed to variations in the crystallinity of the samples upon Zn incorporation. X-Ray diffraction patterns reveals that all the films are polycrystalline in nature having tetragonal rutile structure. The band gap energy values decreased from 3.71 eV to 3.30 eV with increase in the Zn concentration due to formation of defect states and atomic structural disordering. The surface morphology and average surface roughness of the samples were investigated using Atomic force microscopy which endorses the shift from the crystalline state to the amorphous state. The sign and magnitude of nonlinear refractive index and nonlinear absorption coefficient was found out by Z-scan technique with a continuous wave laser as the excitation source. The third order optical Susceptibility χ(3) has found to be increased from 1.08 × 10−3 esu to 2.20 × 10−3 esu upon Zn incorporation. The Z-scan results reveal that the films exhibit self-defocusing nonlinearity. Enhancement in the optical nonlinearity upon doping enables the applicability of the material in various optoelectronic device applications.

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