Titanium (III) reduction of dimethylglyoxime: Electrochemical and kinetic studies

M. P. Yashoda, Padmalatha, B. S. Sherigara, P. V. Nayak

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

Titanium (III) mediated electroreduction of dimethyl glyoxime has been carried out in aqueous sulphuric acid medium and the reduction product has been isolated and characterised. The kinetic investigations have been carried out under stoichiometric and non-stoichiometric conditions at 306K. It has been found that the reaction follows overall second order kinetics, first order each in [Ti(III)] and [DMG] and fractional order in sulphuric acid. The effect of varying concentrations of Ti(III), DMG, H2SO4, ionic strength, and solvent composition has been studied. Effect of temperature has also been studied and activation parameters have been computed from Arrhenius and Eyring plots.

Original languageEnglish
Pages (from-to)176-179
Number of pages4
JournalIndian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry
Volume38
Issue number2
Publication statusPublished - 02-1999

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Titanium
titanium
acids
Kinetics
Acids
kinetics
Ionic strength
plots
Chemical activation
activation
products
Chemical analysis
Temperature
temperature
dimethylglyoxime

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

Cite this

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abstract = "Titanium (III) mediated electroreduction of dimethyl glyoxime has been carried out in aqueous sulphuric acid medium and the reduction product has been isolated and characterised. The kinetic investigations have been carried out under stoichiometric and non-stoichiometric conditions at 306K. It has been found that the reaction follows overall second order kinetics, first order each in [Ti(III)] and [DMG] and fractional order in sulphuric acid. The effect of varying concentrations of Ti(III), DMG, H2SO4, ionic strength, and solvent composition has been studied. Effect of temperature has also been studied and activation parameters have been computed from Arrhenius and Eyring plots.",
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Titanium (III) reduction of dimethylglyoxime : Electrochemical and kinetic studies. / Yashoda, M. P.; Padmalatha; Sherigara, B. S.; Nayak, P. V.

In: Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry, Vol. 38, No. 2, 02.1999, p. 176-179.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Titanium (III) reduction of dimethylglyoxime

T2 - Electrochemical and kinetic studies

AU - Yashoda, M. P.

AU - Padmalatha,

AU - Sherigara, B. S.

AU - Nayak, P. V.

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AB - Titanium (III) mediated electroreduction of dimethyl glyoxime has been carried out in aqueous sulphuric acid medium and the reduction product has been isolated and characterised. The kinetic investigations have been carried out under stoichiometric and non-stoichiometric conditions at 306K. It has been found that the reaction follows overall second order kinetics, first order each in [Ti(III)] and [DMG] and fractional order in sulphuric acid. The effect of varying concentrations of Ti(III), DMG, H2SO4, ionic strength, and solvent composition has been studied. Effect of temperature has also been studied and activation parameters have been computed from Arrhenius and Eyring plots.

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